458139

tert-Butylhydroperoxid -Lösung

70 wt. % in H₂O

• Synonym(e): Luperox^® TBH70X, T-HYDRO^® -Lösung, 1,1-Dimethylethyl-hydroperoxid, 2-Hydroperoxy-2-methylpropan, TBHP
• Lineare Formel: (CH₃)₃COOH
• CAS-Nummer: 75-91-2
• Molekulargewicht: 90.12
• Beilstein: 1098280
• MDL-Nummer: MFCD00002130
• UNSPSC-Code: 12162002
• PubChem Substanz-ID: 24869433
• NACRES: NA.23

Eigenschaften

• Form: liquid
• Qualitätsniveau: 200
• Eignung der Reaktion: reaction type: C-H Activation; reagent type: catalyst; reagent type: oxidant
• Konzentration: 12.25-13.31% (active oxygen); 69.0-75.0% (Na₂S₂O₃, titration); 70 wt. % in H₂O
• Brechungsindex: n20/D 1.386
• pH-Wert: 4.3
• bp: 96.2 °C
• Dichte: 0.93 g/mL at 25 °C
• Lagertemp.: 2-8°C
• SMILES String: CC(C)(C)OO
• InChI: 1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
• InChIKey: CIHOLLKRGTVIJN-UHFFFAOYSA-N

Beschreibung

Anwendung

Versatile reagent for oxidations.

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Rechtliche Hinweise

Product of Arkema Inc.

Sicherheitshinweise

• Piktogramme: GHS02,GHS06,GHS08,GHS05,GHS09
• Signalwort: Danger
• H-Sätze: H226,H242,H302,H311,H314,H317,H330,H335,H341,H411
• P-Sätze: P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378
• Gefahreneinstufungen: Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 5.2 - Organic peroxides and self-reacting hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): 107.6 °F - closed cup
• Flammpunkt (°C): 42 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter