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704326

Sigma-Aldrich

[6.6] Diphenyl C62 bis(Buttersäuremethylester)(Isomerengemisch)

99.5%

Synonym(e):

Bis-(1-[3-(methoxycarbonyl)-propyl]-1-phenyl)-[6.6]C62 Isomerengemisch, Bis[60]PCBM

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About This Item

Empirische Formel (Hill-System):
C84H28O4
Molekulargewicht:
1101.12
UNSPSC-Code:
12352103
NACRES:
NA.23

Assay

99.5%

Form

solid

mp (Schmelzpunkt)

>300 °C

Löslichkeit

organic solvents: soluble

SMILES String

COC(=O)CCCC2(c1ccccc1)C34c5c6c7c8c9c%10c(c%11c%12c3c%13c5c%14c%15c6c%16c7c%17c9c%18c%19c%20c%21c%22c%23c%24c%25c%26c%27c%28c%29c(c%20c%30c%18c%10c%31c%11c%32c%12c%33c%13c(c%26c%33c%28c%32c%29c%30%31)c%14c%25c%15c%23c%16c%22c%17%19)C%21%34C(CCCC(=O)OC)(c%35ccccc%35)C%24%27%34)C248

Allgemeine Beschreibung

Bis[60]PCBM is a fullerene derivative.
[6.6] Diphenyl C62bis(butyric acid methyl ester)(mixture of isomers) (bis-[60]PCBM) is a fullerene based acceptor molecule that is a bis analog of PCBM. It can be used in polymeric solar cells to improve the open circuit voltage (Voc).

Anwendung

Soluble n-channel organic semiconductor. Used in polymer:fullerene bulk heterojunction solar cells.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Analysenzertifikate (COA)

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C60 Pyrrolidin-Trisäure-Ethylester 97% (HPLC)

Sigma-Aldrich

709093

C60 Pyrrolidin-Trisäure-Ethylester

Buckminsterfulleren C60 99.5%

Sigma-Aldrich

379646

Buckminsterfulleren C60

Material solubility effects in bulk heterojunction solar cells based on the bis-cyclopropane fullerene adducts and P3HT
Susarova DK, et al.
Solar Energy Materials and Solar Cells, 120(17), 30-36 (2014)
Purification and electronic characterisation of 18 isomers of the OPV acceptor material bis-[60] PCBM
Shi W, et al.
Chemical Communications (Cambridge, England), 53(5), 975-978 (2017)
M. Lenes, G.AH. Weltzelaer, F.B. Kooistra, S.C. Veenstra, J.C. Hummelen, P.W.M. Blom
Advanced Mat., 20, 2116-2116 (2008)
Isomer-Pure Bis-PCBM-Assisted Crystal Engineering of Perovskite Solar Cells Showing Excellent Efficiency and Stability
Zhang F, et al.
Advanced Materials, 29(17), 1606806-1606806 (2017)

Artikel

Fullerene-Based n-Type Semiconductors in Organic Electronics

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Optoelectronic Devices Based on Diketopyrrolopyrrole (DPP)-containing Conjugated Small Molecules

Optoelectronic Devices Based on Diketopyrrolopyrrole (DPP)-containing Conjugated Small Molecules

Polymer-Sorted Semiconducting Carbon Nanotubes for Transistors and Solar Cells

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