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684457

Sigma-Aldrich

[6,6]-Phenyl C61 Buttersäuremethylester

>99.9%

Synonym(e):

1-[3-(Methoxycarbonyl)-propyl]-1-phenyl[6.6]C61, 3′H-Cyclopropa[1,9] [5,6]fulleren-C60-Ih-3′-buttersäure-3′-phenyl-methylester, PCBM, [60]PCBM

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About This Item

Empirische Formel (Hill-System):
C72H14O2
CAS-Nummer:
160848-22-6
Molekulargewicht:
910.88
MDL-Nummer:
MFCD07784544
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24885806
NACRES:
NA.23

Beschreibung

functionalized fullerene

Qualitätsniveau

100

Assay

>99.9%

Form

solid

Löslichkeit

chlorobenzene: soluble
organic solvents: soluble
toluene: soluble

Energie der Orbitale

HOMO 6.1 eV 
LUMO 3.7 eV 

Halbleitereigenschaften

N-type (mobility=0.21 cm2/V·s)

SMILES String

COC(=O)CCCC2(c1ccccc1)[C]3=4c5c6c7c8c9c%10c(c%11c%12c3c%13c5c%14c%15c6c%16c7c%17c9c%18c%19c%10c%20c%11c%21c%12c%22c%13c%23c%14c%24c%15c%25c%16c%26c%17c%18c%27c%28c%19c%20c%29c%21c%30c%22c%23c%31c%24c%32c%25c%26c%27c%33c%28c%29c%30c%31c%32%33)[C]2=48

InChI

1S/C72H14O2/c1-74-11(73)8-5-9-70(10-6-3-2-4-7-10)71-66-59-52-40-32-23-14-12-13-15-18(14)27-34(32)42-43-35(27)33-24(15)26-22-17(13)20-19-16(12)21-25(23)38(40)46-44-30(21)28(19)36-37-29(20)31(22)45-47-39(26)41(33)53-55(43)64(63(66)54(42)52)67-60(53)58(47)62-51(45)49(37)56-48(36)50(44)61(57(46)59)68(71)65(56)69(62)72(67,70)71/h2-4,6-7H,5,8-9H2,1H3

InChIKey

MCEWYIDBDVPMES-UHFFFAOYSA-N

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Allgemeine Beschreibung

[6,6]-Phenyl C61 butyric acid methyl ester ([60]PCBM) is a methanofullerene that has a better solubility in organic solvents than fullerenes(C60). It has high electron mobility which enables its function as an electron acceptor in electrochemical applications.

Anwendung

[60]PCBM is an n-type semi-conductor widely used as an electron transport material with low cost and high surface area in different energy based applications like organic photovoltaics (OPVs), perovskite solar cells (PSCs), field effect transistors (FETs) and photodetectors.
Löslicher organischer n-Kanal-Halbleiter. Zur Verwendung als n-leitende Schicht in der Kunststoffelektronik, insbesondere OFETs mit Bulk-Heteroübergang und Photovoltaikzellen (PVs).

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
MKCJ8649
MKCH2062
MKCD7953
MKCB1242V
MKBX7366V

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PTB7 average Mw 80,000-200,000, PDI ≤3.0

Sigma-Aldrich

772410

PTB7

Enhancement of organic photovoltaic device performance via P3HT: PCBM solution heat treatment.
Otieno F, et al.
Thin Solid Films, 625(24), 62-69 (2017)
Perovskite-fullerene hybrid materials suppress hysteresis in planar diodes.
Xu J, et al.
Nature Communications, 6(7), 7081-7081 (2015)
(60) PCBM single crystals: remarkably enhanced band-like charge transport, broadband UV-visible-NIR photo-responsivity and improved long-term air-stability.
Zhao X, et al.
Journal of Material Chemistry C, 6(20), 5489-5496 (2018)
Organic Single-Crystalline Donor-Acceptor Heterojunctions with Ambipolar Band-Like Charge Transport for Photovoltaics.
Zhao X, et al.
Advanced Materials Interfaces, 530(24), 1800336-1800336 (2018)
Field-effect transistor structures on the basis of poly (3-hexylthiophene), fullerene derivatives (60) PCBM,(70) PCBM, and nickel nanoparticles.
Aleshin N, et al.
Physics of the Solid State, 58(9), 1882-1890 (2016)
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Artikel

Fullerene-Based n-Type Semiconductors in Organic Electronics

Since the first publication in 1995 describing a bulk heterojunction photodiode incorporating a methanofullerene, significant progress has been made in improving device performance and the scope of device research has broadened widely.

NTz Building Blocks for Organic Semiconductors

The field of organic electronics has emerged as the next-generation technology potentially enabling ultra-thin, large-area, and/or flexible devices, consisting of organic field-effect transistors (OFETs), organic light-emitting diodes (OLEDs), and organic photovoltaics (OPVs).

PCBM-Based n-Type Semiconductors

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Non-Fullerene Acceptors for Organic Photovoltaic Applications

The emerging organic photovoltaic (OPV) technology is very promising for low-cost solar energy production. OPV devices can be produced using high-throughput, large-volume printing methods on lightweight and flexible plastic substrates, making them easy to deploy and use in innovative ways.

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