693030

(S)-T-BINAP

• Synonym(e): (S)-(−)-2,2′-p-Tolyl-phosphino)-1,1′-binaphthyl, (S)-Tol-BINAP
• Empirische Formel (Hill-System): C₄₈H₄₀P₂
• CAS-Nummer: 100165-88-6
• Molekulargewicht: 678.78
• MDL-Nummer: MFCD01311709
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329761556
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Optische Aktivität: [α]20/D -156°, c = 0.5 in benzene
• mp (Schmelzpunkt): 250-255 °C
• Funktionelle Gruppe: phosphine
• InChI: 1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3
• InChIKey: IOPQYDKQISFMJI-UHFFFAOYSA-N

Beschreibung

Anwendung

Takasago Ligands and Complexes for Asymmetric Reactions

(S)-T-BINAP reacts with silver nitrate to form (S)-Tol-BINAP·AgNO₃, which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary alcohols. It may be used as a chiral ligand in the palladium catalyzed asymmetric double carbohydroamination of iodoarenes to form α-aminoamides. It can also catalyze the asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate to form chiral N-allyl ortho-tert-butylanilides.

Rechtliche Hinweise

Sold in collaboration with Takasago for research purposes only.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)