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Merck

668729

Sigma-Aldrich

Diethylzink

packaged for use in deposition systems

Synonym(e):

DEZ, Zinkdiethyl

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About This Item

Lineare Formel:
(C2H5)2Zn
CAS-Nummer:
Molekulargewicht:
123.51
Beilstein:
3587207
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

Form

liquid

Brechungsindex

n20/D 1.498 (lit.)

bp

117 °C (lit.)

mp (Schmelzpunkt)

−28 °C (lit.)

Dichte

1.205 g/mL at 25 °C (lit.)

SMILES String

CC[Zn]CC

InChI

1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;

InChIKey

HQWPLXHWEZZGKY-UHFFFAOYSA-N

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Allgemeine Beschreibung

Atomic number of base material: 30 Zinc

Anwendung

Reacted with water in a low temperature (<200°C) atomic layer deposition of polycrystalline ZnO layers displaying exciton photoluminescence at room temperature.

Signalwort

Danger

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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The straightforward preparation of new modular oxazoline-containing bifunctional catalysts is reported employing a microwave-assisted Buchwald-Hartwig aryl amination as the key step. Covalent attachment of 2-(o-aminophenyl)oxazolines and pyridine derivatives generated in good-to-high yields a series of ligands in two or three
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Journal of the American Chemical Society, 127(47), 16416-16425 (2005-11-25)
There is a great demand for development of catalyst systems that are not only efficient and highly enantioselective but are also environmentally benign. Herein we report investigations into the catalytic asymmetric addition of alkyl and functionalized alkyl groups to ketones
Donna K Friel et al.
Journal of the American Chemical Society, 130(30), 9942-9951 (2008-07-01)
Alkylations of pyridyl-substituted ynones with Et2Zn and Me2Zn, promoted by amino acid-based chiral ligands in the presence of Al-based alkoxides, afford tertiary propargyl alcohols efficiently in 57% to >98% ee. Two easily accessible chiral ligands are identified as optimal for
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Angewandte Chemie (International ed. in English), 48(27), 4982-4985 (2009-06-06)
New uses for ALD: By applying standard metal oxide atomic layer deposition (ALD) to two types of porphyrins, site-specific chemical infiltration of substrate molecules is achieved: Diethylzinc can diffuse into the interior of porphyrin supramolecular structures and induce metalation of

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