499307

Phenethylzinkbromid -Lösung

0.5 M in THF

• Lineare Formel: C₆H₅CH₂CH₂ZnBr
• CAS-Nummer: 308796-14-7
• Molekulargewicht: 250.45
• MDL-Nummer: MFCD01311437
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24873270

Eigenschaften

• Qualitätsniveau: 100
• Konzentration: 0.5 M in THF
• bp: 65 °C
• Dichte: 0.965 g/mL at 25 °C
• Lagertemp.: 2-8°C
• SMILES String: Br[Zn]CCc1ccccc1
• InChI: 1S/C8H9.BrH.Zn/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1
• InChIKey: SEXSOTWHLBYVNF-UHFFFAOYSA-M

Beschreibung

Anwendung

Phenethylzinc bromide can be used as a reagent:

• In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
• To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
• To synthesize benzyl substituted thienopyrimidine derivatives.

Rechtliche Hinweise

Product of Rieke^® Metals, Inc.

Sicherheitshinweise

• Piktogramme: GHS02,GHS07,GHS08
• Signalwort: Danger
• H-Sätze: H225 - H319 - H335 - H336 - H351
• P-Sätze: P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2
• Zusätzliche Gefahrenhinweise: EUH014 - EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 1.4 °F - closed cup
• Flammpunkt (°C): -17 °C - closed cup