46920

N-(Fluorenyl-9-methoxycarbonyloxy)-succinimid

≥98.0% (HPLC), for peptide synthesis

• Synonym(e): 9-Fluorenylmethyl-N-succinimidylcarbonat, Fmoc N-hydroxysuccinimidester, Fmoc-OSu
• Empirische Formel (Hill-System): C₁₉H₁₅NO₅
• CAS-Nummer: 82911-69-1
• Molekulargewicht: 337.33
• Beilstein: 3569540
• EG-Nummer: 433-520-5
• MDL-Nummer: MFCD00010733
• UNSPSC-Code: 12352108
• PubChem Substanz-ID: 57650882
• NACRES: NA.22

Eigenschaften

• product name: N-(Fluorenyl-9-methoxycarbonyloxy)-succinimid, ≥98.0% (HPLC)
• Qualitätsniveau: 200
• Assay: ≥98.0% (HPLC)
• Form: powder
• mp (Schmelzpunkt): 150-153 °C (lit.)
• Anwendung(en): peptide synthesis
• Funktionelle Gruppe: Fmoc; imide
• Lagertemp.: 2-8°C
• SMILES String: O=C(OCC1c2ccccc2-c3ccccc13)ON4C(=O)CCC4=O
• InChI: 1S/C19H15NO5/c21-17-9-10-18(22)20(17)25-19(23)24-11-16-14-7-3-1-5-12(14)13-6-2-4-8-15(13)16/h1-8,16H,9-11H2
• InChIKey: WMSUFWLPZLCIHP-UHFFFAOYSA-N

Beschreibung

Anwendung

Most efficient reagent for the selective preparation of N-(9-fluorenylmethoxycarbonyl) derivatives of hydroxy-amino acids in high yield. Dipeptide formation is lower than with the chloroformate, Fmoc-Cl. It has been employed in the synthesis of glycopeptides.

Sicherheitshinweise

• Piktogramme: GHS07,GHS09
• Signalwort: Warning
• H-Sätze: H302 - H317 - H411
• P-Sätze: P261 - P264 - P273 - P280 - P301 + P312 - P302 + P352
• Gefahreneinstufungen: Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Sens. 1
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)