422002

1,6-Diaminohexan

technical grade, 70%

• Synonym(e): 1,6-Hexandiamin, HMDA, Hexamethylendiamin
• Lineare Formel: NH₂(CH₂)₆NH₂
• CAS-Nummer: 124-09-4
• Molekulargewicht: 116.20
• Beilstein: 1098307
• MDL-Nummer: MFCD00008243
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24866408
• NACRES: NA.22

Eigenschaften

• Qualität: technical grade
• Dampfdichte: 4 (vs air)
• Assay: 70%
• Form: liquid
• Expl.-Gr.: 6.3 %
• Methode(n): gas chromatography (GC): suitable
• Brechungsindex: n20/D 1.439 (lit.)
• bp: 111-130 °C
• mp (Schmelzpunkt): 42-45 °C (lit.)
• Löslichkeit: alcohol: soluble(lit.); hydrocarbons: soluble(lit.); water: soluble(lit.)
• Dichte: 0.89 g/mL at 25 °C (lit.)
• SMILES String: NCCCCCCN
• InChI: 1S/C6H16N2/c7-5-3-1-2-4-6-8/h1-8H2
• InChIKey: NAQMVNRVTILPCV-UHFFFAOYSA-N
• Angaben zum Gen: rat ... Ppm1a(24666)

Beschreibung

Allgemeine Beschreibung

Hexamethylenediamine (1,6-Diaminohexane) is a linear aliphatic diamine. It reacts with various inorganic acids to afford mono and diacid salts. It can be prepared from adipic dinitrile via catalytic hydrogenation reaction.

Hexamethylenediamine is a useful industrial intermediate widely used in the production of aliphatic and semi-aromatic polyamides. Analysis of 1,6-hexamethylenediamine (HDA) in aqueous solution, human urine and plasma by capillary gas chromatographic method with thermionic specific detection has been reported.

Anwendung

Hexamethylenediamine (1,6-hexanediamine, HDA ) may be used in the preparation of the following:

• polyamides and their hydrolytic and fungal degradability was investigated
• mullite ceramics
• dialkyl hexamethylene-1,6-dicarbamate (AHDC), via trans-esterification reaction of HDA and alkyl carbamates (AC) using FeCl₃ as catalyst

Sonstige Hinweise

remainder water

Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H302,H314,H335
• P-Sätze: P261 - P270 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 1
• Flammpunkt (°F): 201.2 °F
• Flammpunkt (°C): 94 °C