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Di-(2-picolyl)amin
97%
Synonym(e):
Bis-(2-pyridylmethyl)-amin
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Alle Fotos(3)
About This Item
Empirische Formel (Hill-System):
C12H13N3
CAS-Nummer:
Molekulargewicht:
199.25
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Assay
97%
Brechungsindex
n20/D 1.578 (lit.)
bp
139-141 °C/1 mmHg (lit.)
Löslichkeit
water: soluble (partially miscible)(lit.)
Dichte
1.107 g/mL at 25 °C (lit.)
Funktionelle Gruppe
amine
SMILES String
C(NCc1ccccn1)c2ccccn2
InChI
1S/C12H13N3/c1-3-7-14-11(5-1)9-13-10-12-6-2-4-8-15-12/h1-8,13H,9-10H2
InChIKey
KXZQYLBVMZGIKC-UHFFFAOYSA-N
Verwandte Kategorien
Allgemeine Beschreibung
Di-(2-picolyl)amine (DPA), a secondary amine containing two picolyl substituents, acts as a tridentate ligand due to its three donor nitrogen atoms. It is commonly used in coordination chemistry for the synthesis of binary, ternary, and binuclear complexes with various metal ions, including copper (Cu) and cadmium (Cd).
Anwendung
Di-(2-picolyl)amine can be used as:
- A reactant to synthesize di(2-pyridylmethylamino)alkanoic esters using ω-iodoaliphatic carboxylic esters in the presence of triethylamine.
- A ligand to synthesize iron complexes of di-(2-picolyl)amine by treating with iron trichloride, which can be used to catalyze the direct hydroxylation of benzene to phenol.
- A reagent for the protection of carboxylic acids as carboxamides of bispicolylamine.
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
10 - Combustible liquids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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