309281

Eisen(III)-perchlorat Hydrat

crystalline

• Synonym(e): Perchloric acid iron(III) salt hydrate
• Lineare Formel: Fe(ClO₄)₃ · xH₂O
• CAS-Nummer: 15201-61-3
• Molekulargewicht: 354.20 (anhydrous basis)
• EG-Nummer: 236-908-0
• MDL-Nummer: MFCD00149705
• UNSPSC-Code: 12352000
• PubChem Substanz-ID: 24858725
• NACRES: NA.22

Eigenschaften

• Form: crystalline
• Eignung der Reaktion: reagent type: oxidant
• Verunreinigungen: <0.10% chloride
• Farbe: yellow
• SMILES String: [Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• InChI: 1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
• InChIKey: PFPIMAZLJXJVAN-UHFFFAOYSA-K

Beschreibung

Anwendung

Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

Catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization

Iron(III) perchlorate hydrate is a useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units and in photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution.

It can be used as a catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Fulleroxazolidines
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Sicherheitshinweise

• Piktogramme: GHS03,GHS07
• Signalwort: Danger
• H-Sätze: H272,H315,H319,H335
• P-Sätze: P210 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges