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Merck

229474

Sigma-Aldrich

Bismut(III)-iodid

≥99.998% trace metals basis

Synonym(e):

Bismuth triiodide, Triiodobismuthane

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About This Item

Empirische Formel (Hill-System):
BiI3
CAS-Nummer:
Molekulargewicht:
589.69
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.23

Assay

≥99.998% trace metals basis

Form

powder and chunks

Eignung der Reaktion

reagent type: catalyst
core: bismuth

Verunreinigungen

≤15.0 ppm Trace Metal Analysis

mp (Schmelzpunkt)

408 °C (lit.)

Dichte

5.78 g/mL at 25 °C (lit.)

SMILES String

I[Bi](I)I

InChI

1S/Bi.3HI/h;3*1H/q+3;;;/p-3

InChIKey

KOECRLKKXSXCPB-UHFFFAOYSA-K

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Piktogramme

Corrosion

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Eye Dam. 1 - Skin Corr. 1B

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Mirko Scholz et al.
Physical chemistry chemical physics : PCCP, 20(16), 10677-10685 (2017-12-21)
Trivalent bismuth compounds featuring octahedral halide coordination, such as BiI3, double-perovskite structures and vacancy-ordered perovskite derivatives, have recently attracted considerable attention as potential environmentally benign thin film materials for solar light-harvesting and optoelectronic applications aiming to replace toxic lead-based perovskites.
Wenhua Bi et al.
Chemical communications (Cambridge, England), (44)(44), 5743-5745 (2008-11-15)
The dehydration of a iodobismuthate hybrid built up from Bi(4)I(16) clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI(4) chains and 1D helical molecular chains, highlighting the templating effect
Jie Sun et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(5), 904-908 (2011-05-10)
A novel series of Ge-Te-BiI(3) chalcogenide glasses were prepared by traditional melt-quenching method and the glass-forming region was determined. Properties measurements including density, Vis-NIR and infrared (IR) transmission spectra with FTIR, XRD, DSC were adopted to analyze the composition, structure
F M Abdel-Gawad
Journal of pharmaceutical and biomedical analysis, 16(5), 793-799 (1998-04-16)
A systematic spectrophotometric study on the ion-pair formation of Bi(III)-iodide with amineptine hydrochloride, piribedil and trimebutine maleate is carried out. The optimal experimental conditions pH, concentration of Bi(III) nitrate, potassium iodide; and the nature and amount of organic solvent have
R R Jia et al.
Amino acids, 31(1), 85-90 (2006-04-04)
New bioinorganic complexes of the aspartic acid with the antimony or bismuth triiodide were synthesized by a direct solid-solid reaction at room temperature. The formula of the complex is MI(3)[OOCCH(2)CH(NH(2))CO](2.5) x 2.5H(2)O (M = Sb, Bi). The complex may be

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