15151

1,1-Bis-(phenylsulfonyl)-ethylen

≥98.0% (CH)

• Synonym(e): (Ethene-1,1-diyldisulfonyl)dibenzene, 1,1-Bis(benzenesulfonyl)ethylene, 1,1-Bis(phenylsulfonyl)ethene, 1,1′-[Ethenylidenebis(sulfonyl)]bis[benzene]
• Empirische Formel (Hill-System): C₁₄H₁₂O₄S₂
• CAS-Nummer: 39082-53-6
• Molekulargewicht: 308.37
• Beilstein: 2056786
• MDL-Nummer: MFCD00043149
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 57647326
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: ≥98.0% (CH)
• Form: powder
• mp (Schmelzpunkt): 124-126 °C
• Funktionelle Gruppe: sulfone
• SMILES String: C=C(S(=O)(=O)c1ccccc1)S(=O)(=O)c2ccccc2
• InChI: 1S/C14H12O4S2/c1-12(19(15,16)13-8-4-2-5-9-13)20(17,18)14-10-6-3-7-11-14/h2-11H,1H2
• InChIKey: KABQEPJVQFXVIN-UHFFFAOYSA-N

Beschreibung

Anwendung

1,1-Bis(phenylsulfonyl)ethylene was used in the preparation of α,α-disubstituted alpha-amino acid derivatives.

Sonstige Hinweise

A synthetic equivalent of the ethylene 1,2-dipole; Dienophile for Diels-Alder reactions, review; A useful synthon for neutral homologation of ketones

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)