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700703

Sigma-Aldrich

N-tert-Butyl-N-(2-methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylamine

Synonym(s):

2,2,5-Trimethyl-3-(1-phenylethoxy)-4-phenyl-3-azahexane, Alkoxyamine NMP initiator

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About This Item

Empirical Formula (Hill Notation):
C22H31NO
CAS Number:
227000-59-1
Molecular Weight:
325.49
MDL number:
MFCD12546017
UNSPSC Code:
12162002
PubChem Substance ID:
329762224
NACRES:
NA.23

form

liquid

Quality Level

100

refractive index

n20/D 1.536

density

0.968 g/mL at 25 °C

storage temp.

−20°C

SMILES string

CC(C)C(N(OC(C)c1ccccc1)C(C)(C)C)c2ccccc2

InChI

1S/C22H31NO/c1-17(2)21(20-15-11-8-12-16-20)23(22(4,5)6)24-18(3)19-13-9-7-10-14-19/h7-18,21H,1-6H3

InChI key

FPFRTDOMIFBPBZ-UHFFFAOYSA-N

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Application

Block Copolymer Synthesis Using a Commercially Available NMP Inititator

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN6739
MKCC2057
MKBN3244V
MKBH3384V
MKBF5807V

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Benoit, D., Chaplinski, V., Braslau, R., Hawker, C.J.
Journal of the American Chemical Society, 121, 3904-3904 (1999)

Articles

Block Copolymer Synthesis Using a Nitroxide-mediated Radical Polymerization (NMP) Approach

A detailed article on block copolymer synthesis using a nitroxide-mediated radical polymerization (NMP) approach.

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

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Protocols

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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