367478
O-(tert-Butyldimethylsilyl)hydroxylamine
95%
Synonym(s):
Aminoxy-tert-butyldimethylsilane
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About This Item
Linear Formula:
(CH3)3CSi(CH3)2ONH2
CAS Number:
Molecular Weight:
147.29
Beilstein:
2424306
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
95%
form
solid
bp
87-90 °C/40 mmHg (lit.)
mp
62-65 °C (lit.)
SMILES string
CC(C)(C)[Si](C)(C)ON
InChI
1S/C6H17NOSi/c1-6(2,3)9(4,5)8-7/h7H2,1-5H3
InChI key
SSUCKKNRCOFUPT-UHFFFAOYSA-N
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Application
O-(tert-Butyldimethylsilyl)hydroxylamine (tert-butyldimethylsilyl-O-hydroxylamine) may be used to induce the cleavage, during solid supported synthesis of hydroxamic acids.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Solid supported synthesis of hydroxamic acids.
Golebiowski A and Klopfenstein S.
Tetrahedron Letters, 39(21), 3397-3400 (1998)
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