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18-1605

Sigma-Aldrich

Lithium perchlorate

SAJ special grade, ≥99.0%

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About This Item

Fórmula lineal:
LiClO4
Número de CAS:
7791-03-9
Peso molecular:
106.39
EC Number:
232-237-2
MDL number:
MFCD00011079
UNSPSC Code:
12352302
PubChem Substance ID:
329751640

grade

SAJ special grade

assay

≥99.0%

form

crystalline

reaction suitability

reagent type: oxidant

availability

available only in Japan

pH

6.0-9.5 (25 °C, 106.4 g/L)

mp

236 °C (lit.)

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análisis (COA)

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Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave
L H Sim et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(3-4), 287-292 (2010-05-07)
The interaction behaviours between components of polyacrylate (PAc)/poly(ethylene oxide) (PEO) and lithium perchlorate (LiClO(4)) were investigated in detail by Attenuated Total Reflectance (ATR)-Fourier Transformed Infrared (FTIR) spectroscopy. Solution cast films of the PAc/PEO and PAc/PEO/LiClO(4) were examined. No obvious shifting
Natalia Varaksa et al.
Proceedings of the National Academy of Sciences of the United States of America, 99(8), 5012-5017 (2002-04-18)
The adsorption of the trigonal connector, 1,3,5-tris[10-(3-ethylthiopropyl)dimethylsilyl-1,10-dicarba-closo-decaboran-1-yl]benzene (1), from acetonitrile/0.1 M LiClO(4) on the surface of mercury at potentials ranging from +0.3 to -1.4 V (vs. aqueous Ag/AgCl/1 M LiCl) was examined by voltammetry, Langmuir isotherms at controlled potentials, and
Paula A Brooksby et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 64(2), 372-382 (2005-12-31)
Attenuated total reflection infrared spectroscopy was used to examine the concentration dependent solvation of LiClO4 and NaClO4 electrolytes in propylene carbonate (PC). Factor analysis and curve fitting techniques were performed on the measured spectra and the results compared with ab
Witold Darlewski et al.
Journal of hazardous materials, 175(1-3), 460-467 (2009-11-17)
A process of dibutyl sulphide (DBS) electro-oxidation using electrolysis and cyclic voltamperometry was investigated in water-methanol solution using different electrodes (platinum, boron doped diamond, graphite and glassy carbon). Obtained results indicate that the DBS electro-oxidation process is irreversible in voltamperometric
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