T84603

Triphenylphosphine oxide

98%

• Sinónimos: Ph₃PO, TPPO, Triphenyl phosphorus oxide, Triphenylphosphine monoxide
• Fórmula lineal: (C₆H₅)₃PO
• Número de CAS: 791-28-6
• Peso molecular: 278.28
• Beilstein/REAXYS Number: 745854
• EC Number: 212-338-8
• MDL number: MFCD00002080
• UNSPSC Code: 12352002
• PubChem Substance ID: 24900532
• NACRES: NA.22

Propiedades

• Quality Level: 200
• assay: 98%
• reaction suitability: reagent type: ligand; reaction type: Coupling Reactions; reagent type: ligand; reaction type: Epoxidations; reagent type: ligand; reaction type: Michael Reaction
• mp: 150-157 °C (lit.)
• functional group: phosphine oxide
• SMILES string: O=P(c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C18H15OP/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
• InChI key: FIQMHBFVRAXMOP-UHFFFAOYSA-N

Descripción

Application

Triphenylphosphine oxide can be used:

• As a catalyst in Appel-type chlorination reaction of acyclic primary and secondary alcohols.
• As a catalyst in stereoselective poly and dibromination of α,β-unsaturated esters and β,γ-unsaturated α-ketoester compounds.
• As a promotor in the diastereoselective synthesis of α-ribofuranosides through ribofuranosylation of alcohols with ribofuranosyl iodides.

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H302,H412
• pcodes: P264 - P270 - P273 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 3
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 2
• flash_point_f: 356.0 °F
• flash_point_c: 180 °C
• ppe: dust mask type N95 (US), Eyeshields, Gloves