M54104
Methyl DL-mandelate
97%
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About This Item
Fórmula lineal:
C6H5CH(OH)COOCH3
Número de CAS:
Peso molecular:
166.17
Beilstein/REAXYS Number:
2047558
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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assay
97%
bp
135 °C/12 mmHg (lit.)
mp
54-56 °C (lit.)
SMILES string
COC(=O)C(O)c1ccccc1
InChI
1S/C9H10O3/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8,10H,1H3
InChI key
ITATYELQCJRCCK-UHFFFAOYSA-N
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Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
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Fei Guo et al.
Applied microbiology and biotechnology, 97(8), 3355-3362 (2012-11-28)
Despite directed evolution being a practical and efficient method of improving the properties of enzymes, a trade-off between the targeted property and other essential properties often exists which hinders the efficiency of directed evolution. In our previous work, mutant CVH
Y Chiang et al.
The Journal of organic chemistry, 65(4), 1175-1180 (2000-05-18)
Flash photolysis of methyl phenyldiazoacetate in aqueous solution produced phenylcarbomethoxycarbene, whose hydration generated a short-lived transient species that was identified as the enol isomer of methyl mandelate. This assignment is supported by the shape of the rate profile for decay
Jie-Hua Shi et al.
Journal of molecular modeling, 18(2), 803-813 (2011-05-20)
Host-guest interactions of permethylated β-cyclodextrin (PM-β-CD) with methyl mandelate enantiomers ((R/S)-MMA) were simulated using semiempirical PM3 and ONIOM (B3LYP/6-31G(d):PM3) method. The chiral recognition mechanism of (R/S)-MMA enantiomers on PM-β-CD was investigated. The binding energies for all orientations considered in this
M Y Nie et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 17(10), 1183-1187 (2002-05-07)
Enantiomer separation of mandelates and their analogs, which are important intermediates in asymmetric synthetic and pharmaceutical chemistry, was investigated by capillary gas chromatography using different cyclodextrin derivative chiral stationary phases (CD CSPs). The used cyclodextrin derivatives included permethylated beta-CD (PMBCD)
Han-Ning Wei et al.
Applied biochemistry and biotechnology, 149(1), 79-88 (2008-03-20)
Microorganisms producing lipase were isolated from soil and sewage samples and screened for enantioselective resolution of (R,S)-methyl mandelate to (R)-mandelic acid. A strain designated as GXU56 was obtained and identified as Burkholderia sp. Preparing immobilized GXU56 lipase by simple adsorption
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