Saltar al contenido
MilliporeSigma
Todas las fotos(4)

Key Documents

Otros documentos

F408

Sigma-Aldrich

Ferrocene

98%

Sinónimos:

Bis(cyclopentadienyl)iron, Di(cyclopentadienyl)iron

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
Todas las fotos(4)

About This Item

Fórmula lineal:
Fe(C5H5)2
Número de CAS:
102-54-5
Peso molecular:
186.03
EC Number:
203-039-3
MDL number:
MFCD00001427
UNSPSC Code:
12161600
PubChem Substance ID:
24894802
NACRES:
NA.22

vapor pressure

0.03 mmHg ( 40 °C)

assay

98%

reaction suitability

core: iron
reagent type: catalyst

bp

249 °C (lit.)

mp

172-174 °C (lit.)

λmax

358 nm

storage temp.

2-8°C

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;

InChI key

DFRHTHSZMBROSH-UHFFFAOYSA-N

¿Está buscando productos similares? Visita Guía de comparación de productos

Application

Ferrocene (dicyclopentadienyliron) can be used:
  • As a scaffold for chiral ligands in asymmetric catalysis.
  • In ferrocene-based electrolytes for dye sensitized solar cells applications.
  • In the synthesis of unsymmetrical ferrocene ligands used as catalysts in cross-coupling, hydrogenation, allylic substitution, hydroformylation and aldol reactions.
  • In the synthesis of two-dimensional hexagonally ordered mesoporous carbon (CMK-5) via chemical vapor deposition method, which is used as a catalyst support in oxidation of methanol.
  • In the synthesis of molecular hybrids of ferrocene and fullerene (Bucky ferrocenes).
  • In the preparation of ferrocenium salt which is used as a mild oxidant.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 1 - Flam. Sol. 1 - Repr. 1B - STOT RE 2 Inhalation

target_organs

Liver

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

The syntheses and catalytic applications of unsymmetrical ferrocene ligands
Atkinson RCJ, et al.
Chemical Society Reviews, 33(33), 313-328 (2004)
Muneebah Adams et al.
Dalton transactions (Cambridge, England : 2003), 42(13), 4677-4685 (2013-01-31)
A series of aryl-functionalized and ferrocenyl monothiosemicarbazone compounds (L1-L4) were synthesized in moderate yields via a general Schiff-base condensation reaction. The thiosemicarbazone (TSC) ligands were reacted with the ruthenium dimer [Ru(Ar)(μ-Cl)Cl](2) (Ar = benzene; p-cymene) to yield a series of
Sumit Kumar et al.
ACS omega, 3(9), 12106-12113 (2018-10-16)
1H-1,2,3-Triazole tethered imidazole-isatin and imidazole-isatin-thiosemicarbazone conjugates were synthesized and evaluated against MCF-7 and MDA-MB-231 cell lines. Antiproliferative activities of the synthesized conjugates revealed an optimum combination of longer alkyl chain length as spacer and a halogen-substituent on the isatin ring
Applications of ferrocenium salts in organic synthesis
Toma S and Sebesta R
Synthesis, 12(47), 1683-1695 (2015)
Hybrid of ferrocene and fullerene
Sawamura M, et al.
Journal of the American Chemical Society, 32(124), 9354-9355 (2002)
Ver todos los artículos relacionados

Artículos

Ferrocenylmethyl Methacrylate for Functional Polymers

Ferrocenylmethyl Methacrylate for Functional Polymers

Molecular Layer Deposition of Organic and Hybrid Organic-Inorganic Polymers

Atomic layer deposition (ALD) techniques have emerged in the last ten years to meet various needs including semiconductor device miniaturization, conformal deposition on porous structures and coating of nanoparticles. ALD is based on two sequential self-limiting surface reactions.

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico