923508

(iPrMPhos)PdCl₂

1:1 complex with CH₂Cl₂, ≥95%

• Sinónimos: 1-Diadamantylphosphino-1′-diisopropylphosphinoferrocene palladium dichloride
• Fórmula empírica (notación de Hill): C₃₆H₅₂Cl₂FeP₂Pd
• Peso molecular: 779.92
• UNSPSC Code: 12352103
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: ≥95%
• form: powder
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings
• mp: >300 °C
• SMILES string: Cl[Pd](Cl)([P](c1cccc1)(C23C[C@H]4C[C@H](C[C@H](C4)C3)C2)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5)[P](c8cccc8)(C(C)C)C(C)C.[Fe]

Descripción

Application

(iPrMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (iPrMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable