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746347

Sigma-Aldrich

Dichlorotriphenylphosphine[2-(diphenylphosphino)-N-(2-pyridinylmethyl)ethanamine]ruthenium(II)

greener alternative

97%

Sinónimos:

Ru-PNN catalyst

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About This Item

Fórmula empírica (notación de Hill):
C38H36Cl2N2P2Ru
Número de CAS:
1388712-91-1
MDL number:
MFCD26960800
UNSPSC Code:
12161600
PubChem Substance ID:
329765760
NACRES:
NA.22

assay

97%

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

275-295 °C

greener alternative category

Aligned,

SMILES string

Cl[Ru]Cl.[H]N(CCP(C1=CC=CC=C1)C2=CC=CC=C2)CC3=NC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6

InChI

1S/C20H21N2P.C18H15P.2ClH.Ru/c1-3-10-19(11-4-1)23(20-12-5-2-6-13-20)16-15-21-17-18-9-7-8-14-22-18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h1-14,21H,15-17H2;1-15H;2*1H;/q;;;;+2/p-2

InChI key

JFYJJNHKCBDTMZ-UHFFFAOYSA-L

Categorías relacionadas

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCQ3302
MKBQ2005V

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Artículos

Ester Hydrogenation

Learn about Ester Hydrogenation from MilliporeSigma. The reduction of esters to alcohols is typically accomplished using metal hydrides. While effective, it comes at the cost of stoichiometric waste and complicated workup procedures.

Contenido relacionado

Gusev Group – Professor Product Portal

Prof. Dmitry Gusev and his co-workers are developing organometallic compounds of transition metals with tridentate ('pincer'-type) ligands for applications in catalytic hydrogenation of compounds with polar C=O and C=N bonds, dehydrogenative coupling and dehydrogenation reactions of alcohols.

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

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