594768

4-Methoxycarbonylphenylboronic acid pinacol ester

97%

• Sinónimos: 4-Carbomethoxyphenylboronic acid pinacol ester, Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
• Fórmula empírica (notación de Hill): C₁₄H₁₉BO₄
• Número de CAS: 171364-80-0
• Peso molecular: 262.11
• MDL number: MFCD02179438
• UNSPSC Code: 12352103
• PubChem Substance ID: 24881534
• NACRES: NA.22

Propiedades

• assay: 97%
• form: solid
• mp: 77-81 °C (lit.)
• functional group: ester
• SMILES string: COC(=O)c1ccc(cc1)B2OC(C)(C)C(C)(C)O2
• InChI: 1S/C14H19BO4/c1-13(2)14(3,4)19-15(18-13)11-8-6-10(7-9-11)12(16)17-5/h6-9H,1-5H3
• InChI key: REIZEQZILPXYKS-UHFFFAOYSA-N

Descripción

Application

4-Methoxycarbonylphenylboronic acid pinacol ester can be used as a reagent:   

• In Suzuki–Miyaura cross-coupling reaction with aryl halides to form C-C bonds.     
• For the synthesis of biphenyl derivatives by selective ortho C-H arylation of ketones using Rh catalyst.

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)