562289

3,5-Dichlorophenylmagnesium bromide solution

0.5 M in THF

• Fórmula lineal: Cl₂C₆H₃MgBr
• Número de CAS: 82297-90-3
• Peso molecular: 250.20
• MDL number: MFCD01319892
• UNSPSC Code: 12352103
• PubChem Substance ID: 24880024
• NACRES: NA.22

Propiedades

• reaction suitability: reaction type: Grignard Reaction
• Quality Level: 100
• concentration: 0.5 M in THF
• bp: 65 °C
• density: 0.972 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: Clc1cc(Cl)cc([Mg]Br)c1
• InChI: 1S/C6H3Cl2.BrH.Mg/c7-5-2-1-3-6(8)4-5;;/h2-4H;1H;/q;;+1/p-1
• InChI key: PWOVECVCCCTJFQ-UHFFFAOYSA-M

Descripción

Application

3,5-Dichlorophenylmagnesium bromide can be used:

• In one of the key synthetic steps for the preparation of non-alternant polycyclic hydrocarbon named indeno-benzophenalene.
• As a substrate in the synthesis of carboxylic esters by reacting with 2-methyl-4,6-pyrimidyl dicarbonates.
• As a substrate in the synthesis of aryl ketones by reacting with acid chlorides using bis[2-(N,N-dimethylamino)ethyl] ether ligand.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Información de seguridad

• pictograms: GHS02,GHS05,GHS07,GHS08
• signalword: Danger
• hcodes: H225 - H302 - H314 - H335 - H336 - H351
• pcodes: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
• supp_hazards: EUH014 - EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: -6.2 °F - closed cup
• flash_point_c: -21.2 °C - closed cup