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  • A Pd(II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles.

A Pd(II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles.

Journal of the American Chemical Society (2009-08-25)
Shunsuke Chiba, Yan-Jun Xu, Yi-Feng Wang
PMID19697931
ABSTRACT

A Pd(II)-catalyzed ring expansion-reaction of cyclic 2-azidoalcohol derivatives was found to proceed via an unprecedented C-C bond cleavage-C-N bond formation sequence, providing substituted azaheterocycles.

MATERIALS
Product Number
Brand
Product Description
697230
Sigma-Aldrich
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)