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Photophysical properties of three coordinated copper(i) complexes bearing 1,10-phenanthroline and a monodentate phosphine ligand.

Dalton transactions (Cambridge, England : 2003) (2017-10-19)
Daichi Kakizoe, Michihiro Nishikawa, Yasuo Fujii, Taro Tsubomura
ABSTRACT

We report the synthesis and photophysical properties of Cu(i) complexes with 1,10-phenanthroline (phen) and monodentate phosphine ligands. Single crystal X-ray structural analysis revealed that these have three-coordinated trigonal planar geometries. We also found that one of them, [Cu(phen)(Johnphos)]BF

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Tetrakis(acetonitrile)copper(I) tetrafluoroborate, 97%
Sigma-Aldrich
JohnPhos, 97%
Sigma-Aldrich
Tri(o-tolyl)phosphine, 97%
Sigma-Aldrich
1,10-Phenanthroline, ≥99%
Sigma-Aldrich
Tris(3,5-dimethylphenyl)phosphine, 96%
Sigma-Aldrich
CyJohnPhos, 97%