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Merck
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Key Documents

237051

Sigma-Aldrich

氯化铝

ReagentPlus®, 99%

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About This Item

線性公式:
AlCl3
CAS號碼:
分子量::
133.34
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
eCl@ss:
38120507
PubChem物質ID:
NACRES:
NA.21

蒸汽壓力

1 mmHg ( 100 °C)

產品線

ReagentPlus®

化驗

99%

形狀

powder

反應適用性

reagent type: catalyst
core: aluminum

pH值

2.4 (20 °C, 100 g/L)

mp

190 °C (lit.)

SMILES 字串

Cl[Al](Cl)Cl

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

InChI 密鑰

VSCWAEJMTAWNJL-UHFFFAOYSA-K

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一般說明

氯化铝是一种醇溶性路易斯酸。† 氯化铝与硼氢化钠在二甘醇中以摩尔比混合,得到具有强还原性属性混合物。† 据报道,它促进 4-丁基苯甲酰氯与均三甲苯之间的 Friedel-Crafts 酰化反应。†

應用

氯化铝用于以下研究:
  • 苯聚合生成 p-聚苯。
  • 作为 buckymetallocenes 与酸氯化物的 Friedel-Crafts 酰化的催化剂。
  • 作为用于测定脂质氢过氧化物的比色法微量测定的催化剂。

特點和優勢

氢与其他金属卤化物的气相共还原作用可用于金属间的精细分离,可作为结构材料或化合物使用,具有重要热电、磁和抗氧化性能。 氮化铝可以由添加了AlCl3 的元素合成,以促进结晶。

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

安全危害

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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存取文件庫

Detection of Alternative Oxidase Expression in Arabidopsis thaliana Protoplasts Treated with Aluminium.
Liu J, et al.
Bio-protocol, 5(13) (2015)
p-Polyphenyl from Benzene-Lewis Acid Catalyst-Oxidant. Reaction Scope and Investigation of the Benzene-Aluminum Chloride-Cupric Chloride System1.
Kovacic P and Oziomek J.
The Journal of Organic Chemistry, 29(1), 100-104 (1964)
Shutao Wang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(4), 1700712-1700712 (2018-05-04)
In the search for low-cost and large-scale stationary storage of electricity, nonaqueous aluminum chloride-graphite batteries (AlCl3-GBs) have received much attention due to the high natural abundances of their primary constituents, facile manufacturing, and high energy densities. Much research has focused
Yutaka Matsuo et al.
Dalton transactions (Cambridge, England : 2003), 43(20), 7407-7412 (2013-10-26)
Acylated buckyferrocene and ruthenocene, Fe(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me, Ph, and CH[double bond, length as m-dash]CHPh) and Ru(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me and Ph), were obtained by Friedel-Crafts acylation of the parent buckymetallocenes with the corresponding acid chlorides and aluminum chloride in
Rajkumar Kore et al.
Dalton transactions (Cambridge, England : 2003), 47(23), 7795-7803 (2018-06-01)
Two solids of differing Lewis acidities, triethylammonium tetrachlorozincate ([HN222]2[ZnCl4]) and AlCl3, have been combined across 0.1 to 0.9 mole fractions (with respect to [HN222]2[ZnCl4]), and homogeneous solid double salts or mixed metal [HN222]2x[(1 - x)AlCl3 + xZnCl4] double salt ionic

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