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Merck
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重要文件

205540

Sigma-Aldrich

碘化亚铜

98%

同義詞:

碘化亚铜

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About This Item

經驗公式(希爾表示法):
CuI
CAS號碼:
分子量::
190.45
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
eCl@ss:
38150105
PubChem物質ID:
NACRES:
NA.21
化驗:
98%
形狀:
powder

蒸汽壓力

10 mmHg ( 656 °C)

品質等級

化驗

98%

形狀

powder

反應適用性

reaction type: click chemistry
reagent type: catalyst
core: copper

mp

605 °C (lit.)

密度

5.62 g/mL at 25 °C (lit.)

SMILES 字串

[Cu+].[I-]

InChI

1S/Cu.HI/h;1H/q+1;/p-1

InChI 密鑰

LSXDOTMGLUJQCM-UHFFFAOYSA-M

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相關類別

應用

硅环丙烷和羰基化合物立体专一性和区域选择性反应最佳催化剂。

相關產品

產品號碼
描述
訂價

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral

標靶器官

Thyroid

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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Alkynyl sulfides and selenides from alkynyl bromides and diorganoyl chalcogenides promoted by copper (I) iodide.
Braga AL, et al.
Tetrahedron Letters, 34(3), 393-394 (1993)
The high-temperature structural behaviour of copper (I) iodide.
Keen DA and Hull S.
Journal of Physics. Condensed Matter : An Institute of Physics Journal, 7(29), 5793-5793 (1995)
Simon P H Mee et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(11), 3294-3308 (2005-03-24)
The combination of copper(I) iodide and cesium fluoride significantly enhances the Stille reaction. After extensive optimisation, a variety of electronically unfavourable and sterically hindered substrates were coupled in very high yields under mild conditions.
Convenient preparation of alkynyl selenides, sulfides and tellurides from terminal alkynes and prenylchalcogenyl halides in the presence of copper (I) iodide.
Braga AL, et al.
Tetrahedron Letters, 34(50), 8041-8042 (1993)
Novel preparation of σ-alkynyl complexes of transition metals by copper (I) iodide-catalysed dehydrohalogenation.
Sonogashira K, et al.
Journal of the Chemical Society. Chemical Communications, 9, 291-292 (1977)

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