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一般說明
可以通过还原溴化铜或CuSO4-NaBr来制备溴化亚铜。在熔融状态下,它呈灰褐色/绿褐色。
應用
一些已报道的溴化铜应用包括:
据报道,其可在CuBr/LiOCH3(甲醇溶液)存在下,将 α-溴- α-氯代羧酸盐还原均耦联为 α, α′二氯琥珀酸二甲酯衍生物。
- 交叉偶联反应中的催化剂。
- Sonogashira耦合中的助催化剂。
- 在炔烃对映选择性加成中的Lewis酸。
- 当与三分子吡啶引发剂进行络合时充当还原剂,从而用于苯乙烯、丙烯酸甲酯和甲基丙烯酸甲酯的受控聚合。
据报道,其可在CuBr/LiOCH3(甲醇溶液)存在下,将 α-溴- α-氯代羧酸盐还原均耦联为 α, α′二氯琥珀酸二甲酯衍生物。
相關產品
產品號碼
描述
訂價
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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