跳轉至內容
Merck
全部照片(1)

Key Documents

235385

Sigma-Aldrich

亚硝酸叔丁酯

90%

同義詞:

1,1-Dimethylethyl nitrite

登入查看組織和合約定價


About This Item

線性公式:
(CH3)3CONO
CAS號碼:
分子量::
103.12
Beilstein:
1209339
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

90%

折射率

n20/D 1.368 (lit.)

bp

61-63 °C (lit.)

溶解度

alcohol: very soluble(lit.)
carbon disulfide: very soluble(lit.)
chloroform: very soluble(lit.)
diethyl ether: very soluble(lit.)
glycerol: insoluble (practically)(lit.)
water: slightly soluble(lit.)

密度

0.867 g/mL at 25 °C (lit.)

官能基

nitroso

儲存溫度

2-8°C

SMILES 字串

CC(C)(C)ON=O

InChI

1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3

InChI 密鑰

IOGXOCVLYRDXLW-UHFFFAOYSA-N

尋找類似的產品? 前往 產品比較指南

一般說明

-亚硝酸丁酯(TBN)是一种有效的NO源。TBN参与将芳基和杂芳基胺通过光催化转化为硒化物。它还参与脂族烯烃的自由基多官能化反应

應用

-亚硝酸丁酯已作为试剂:
  • 用于醇、硫醇、胺和环烷烃的重氮化和亚硝化
  • 用于使用芳基胺制备芳基叠氮化物

其他說明

残留物为 2-甲基-2-丙醇

象形圖

FlameExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

14.0 °F - closed cup

閃點(°C)

-10 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves


從最近期的版本中選擇一個:

分析證明 (COA)

Lot/Batch Number

未看到正確版本?

如果您需要一個特定的版本,您可以透過批號來尋找特定憑證。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

Daisuke Hirose et al.
Beilstein journal of organic chemistry, 9, 1713-1717 (2013-09-26)
Water induces a change in the product of radical multifunctionalization reactions of aliphatic alkenes involving an sp(3) C-H functionalization by an 1,5-hydrogen shift using tert-butyl nitrite and molecular oxygen. The reaction without water, reported previously, gives nitrated γ-lactols, whereas the
tert-Butyl Nitrite.
Liu Y.
Synlett, 2011(08), 1184-1185 (2011)
Karine Barral et al.
Organic letters, 9(9), 1809-1811 (2007-03-30)
[reaction: see text] An efficient and improved procedure for the preparation of aromatic azides and their application in the Cu(I)-catalyzed azide-alkyne 1,3-dipolar cycloaddition ("click reaction") is described. The synthesis of aromatic azides from the corresponding amines is accomplished under mild
Debasish Kundu et al.
Organic letters, 16(6), 1814-1817 (2014-03-14)
A novel strategy for the direct conversion of aryl- and heteroarylamines to selenides has been developed via diazotization of amines with tert-butyl nitrite in neutral medium followed by reaction with diaryl/diheteroaryl/dialkyl diselenides in one pot under photocatalysis at room temperature
The Journal of Organic Chemistry, 42, 2431-2431 (1977)

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務