推薦產品
品質等級
化驗
97%
折射率
n20/D 1.402 (lit.)
bp
155-160 °C (lit.)
密度
0.876 g/mL at 25 °C (lit.)
SMILES 字串
CCOC(CC)(OCC)OCC
InChI
1S/C9H20O3/c1-5-9(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3
InChI 密鑰
FGWYWKIOMUZSQF-UHFFFAOYSA-N
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應用
Triethyl orthopropionate is commonly used in the Claisen rearrangement to construct new C-C bonds. It can react with pyrrole and chloroacetic acid to form 1,1,1- [tri-(pyrrol-2-yl)]propane.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
140.0 °F - closed cup
閃點（°C）
60 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Acyclic stereoselection. 44. Diastereoselectivity in the ortho ester Claisen rearrangement of chiral propargylic alcohols. Use of. beta.-allenic esters as chiral methylmalonaldehyde synthons.
Henderson M A and Heathcock C H
The Journal of Organic Chemistry, 53(20), 4736-4745 (1988)
Reactions between pyrrole and orthoesters: preparation of tri-(pyrrol-2-yl) alkanes.
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The Johnson-Claisen rearrangement of 3-hydroxy-2-methylenealkanenitriles: Stereoselective synthesis of functionalized trisubstituted alkenes.
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Claisen rearrangement of (Z)-3-deoxy-3-C-[(hydroxymethyl) methylene]-1, 2: 5, 6-di-O-isopropylidene-. alpha.-D-ribo-hexofuranose with triethyl orthopropionate.
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The Journal of Organic Chemistry, 54(5), 1223-1227 (1989)
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