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Merck
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重要文件

CF0002

Sigma-Aldrich

1-Fluoro-3,3-dimethylbenziodoxole

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About This Item

線性公式:
C9H10FIO
CAS號碼:
MDL號碼:
分類程式碼代碼:
12352101
NACRES:
NA.22

形狀

solid

反應適用性

reaction type: C-C Bond Formation

SMILES 字串

[I]1(OC(c2c1cccc2)(C)C)F

InChI

1S/C9H10FIO/c1-9(2)7-5-3-4-6-8(7)11(10)12-9/h3-6H,1-2H3

InChI 密鑰

FISITPXJYDTLHI-UHFFFAOYSA-N

應用

1-Fluoro-3,3-dimethylbenziodoxole is a crystalline, off-white solid which can be handled under air for extended periods without noticeable hydrolytic decomposition. In the presence of excess fluoride ions (provided by triethylamine-hydrogen fluoride complexes), it can effectively function as an electrophilic fluorination reagent for easily enolizable diketo substrates, or it can engage in silver catalyzed difluorination of styrenes.

Automate your fluorination reactions with Synple Automated Synthesis Platform (SYNPLE-SC002)

法律資訊

Product of CF Plus Chemicals.

象形圖

Flame over circle

訊號詞

Danger

危險聲明

防範說明

危險分類

Ox. Sol. 2

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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文章

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

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