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Key Documents

928917

Sigma-Aldrich

[CF3]8-DPPF

≥95%

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About This Item

經驗公式(希爾表示法):
C42H20F24FeP2
CAS號碼:
分子量::
1098.36
NACRES:
NA.21

品質等級

化驗

≥95%

形狀

powder

反應適用性

reagent type: ligand

mp

154-155 °C

官能基

phosphine

SMILES 字串

C[Fe]C.FC(C1=CC(C(F)(F)F)=CC(P(C2=CC(C(F)(F)F)=CC(C(F)(F)F)=C2)c3cccc3)=C1)(F)F.FC(C4=CC(C(F)(F)F)=CC(P(C5=CC(C(F)(F)F)=CC(C(F)(F)F)=C5)c6cccc6)=C4)(F)F

應用

[CF3]8-DPPF is a ferrocenyl phosphine ligand used in a mild Ni catalyzed C-N cross coupling reaction.

相關產品

產品號碼
描述
訂價

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Richard Y Liu et al.
Journal of the American Chemical Society, 142(9), 4500-4507 (2020-02-11)
Palladium-catalyzed amination reactions using soluble organic bases have provided a solution to the many issues associated with heterogeneous reaction conditions. Still, homogeneous C-N cross-coupling approaches cannot yet employ bases as weak and economical as trialkylamines. Furthermore, organic base-mediated methods have

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