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About This Item
經驗公式(希爾表示法):
C71H73ClN2O2P2Ru
CAS號碼:
分子量::
1184.82
MDL號碼:
分類程式碼代碼:
12352116
NACRES:
NA.22
推薦產品
品質等級
形狀
powder
反應適用性
reagent type: ligand
官能基
phosphine
SMILES 字串
[Ru+]c9c(ccc(c9)OC)C(N)([C@H](N)C(C)C)c%10ccc(cc%10)OC.P(c8cc(cc(c8)C)C)(c7cc(cc(c7)C)C)c1c(c6c(cc1)cccc6)c2c3c(ccc2P(c5cc(cc(c5)C)C)c4cc(cc(c4)C)C)cccc3.[Cl-]
InChI
1S/C52H48P2.C19H25N2O2.ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-
InChI 密鑰
VBDGCLWXZBVBHR-LOJLRZLHSA-M
應用
(R)-RUCY™-XylBINAP is a ruthenabicyclic complex that shows excellent activity in the asymmetric hydrogenation of ketones.
法律資訊
Product of Takasago.
For research and development purposes only. PCT/JP2010/072838
For research and development purposes only. PCT/JP2010/072838
RUCY is a trademark of Takasago Intl. Corp.
相關產品
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
Kazuhiko Matsumura et al.
Journal of the American Chemical Society, 133(28), 10696-10699 (2011-06-17)
A novel ruthenabicyclic complex with base shows excellent catalytic activity in the asymmetric hydrogenation of ketones. The turnover frequency of the hydrogenation of acetophenone reaches about 35,000 min(-1) in the best case, affording 1-phenylethanol in >99% ee. Several aliphatic and
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