901126

trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride

95%

• 同義詞: trans-(PBn₃)₂Ni(o-tolyl)Cl
• 經驗公式（希爾表示法）: C₄₉H₄₉ClNiP₂
• CAS號碼: 1594112-87-4
• 分子量：: 794.01
• 分類程式碼代碼: 12352200

屬性

• 化驗: 95%
• 形狀: powder or solid
• 反應適用性: reaction type: Cross Couplings; reagent type: catalyst
• mp: 200-205 °C
• SMILES 字串: Cl[Ni](C1=C(C)C=CC=C1)(P(CC2=CC=CC=C2)(CC3=CC=CC=C3)CC4=CC=CC=C4)P(CC5=CC=CC=C5)(CC6=CC=CC=C6)CC7=CC=CC=C7

描述

應用

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)_2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

其他說明

• Technology Spotlight: Jamison Nickel (II) Precatalysts
• A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法律資訊

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

安全資訊

• 儲存類別代碼: 13 - Non Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°C）: Not applicable