901165

trans-Bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride

≥95%

• 同義詞: trans-(PCy₃)₂Ni(o-tolyl)Cl
• 經驗公式（希爾表示法）: C₄₃H₇₃ClNiP₂
• CAS號碼: 123839-28-1
• 分子量：: 746.13
• 分類程式碼代碼: 12352200

屬性

• 化驗: ≥95%
• 形狀: powder or solid
• 反應適用性: core: nickel; reaction type: Cross Couplings; reagent type: catalyst
• mp: >300 °C
• SMILES 字串: Cl[Ni](C1=C(C)C=CC=C1)(P(C2CCCCC2)(C3CCCCC3)C4CCCCC4)P(C5CCCCC5)(C6CCCCC6)C7CCCCC7

描述

應用

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

其他說明

• Technology Spotlight: Jamison Nickel (II) Precatalysts
• A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法律資訊

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

安全資訊

• 儲存類別代碼: 4.1B - Flammable solid hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°C）: Not applicable