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900275

Sigma-Aldrich

(t-Bu)PhCPhos

95%

同義詞:

2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl

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About This Item

經驗公式（希爾表示法）:
C26H33N2P
CAS號碼:
1660153-91-2
分子量：:
404.53
MDL號碼:
MFCD29905429
分類程式碼代碼:
12352200
NACRES:
NA.22

品質等級

100

化驗

95%

形狀

powder or crystals

反應適用性

reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand

mp

112 °C

官能基

phosphine

SMILES 字串

P(C(C)(C)C)(c2c(cccc2)c3c(cccc3N(C)C)N(C)C)c1ccccc1

InChI

1S/C26H33N2P/c1-26(2,3)29(20-14-9-8-10-15-20)24-19-12-11-16-21(24)25-22(27(4)5)17-13-18-23(25)28(6)7/h8-19H,1-7H3

InChI 密鑰

HTHOMNNVAUPLKK-UHFFFAOYSA-N

相關類別

應用

(t-Bu)PhCPhos is the Pd G3 complex, from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H413

危險分類

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number

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Paula Ruiz-Castillo et al.
Journal of the American Chemical Society, 137(8), 3085-3092 (2015-02-05)
We report the Pd-catalyzed arylation of very hindered α,α,α-trisubstituted primary amines. Kinetics-based mechanistic analysis and rational design have led to the development of two biarylphosphine ligands that allow the transformation to proceed with excellent efficiency. The process was effective in

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