推薦產品
形狀
solid
品質等級
環保替代產品特色
Catalysis
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mp
48 °C
環保替代類別
儲存溫度
2-8°C
SMILES 字串
CC(C(C)(C)O1)(C)OB1CB2OC(C)(C)C(C)(C)O2
InChI
1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3
InChI 密鑰
MQYZGGWWHUGYDR-UHFFFAOYSA-N
相關類別
一般說明
Bis[(pinacolato)boryl]methane is an aryl boronate ester.
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應用
Bis-boronate has been reported by Morken and coworkers to be a key building block in the synthesis of enantioenriched secondary boronate esters, which undergo facile Suzuki-Miyaura coupling with minimal erosion of enantiopurity.
Bis[(pinacolato)boryl]methane may be used in the preparation of trans-vinyl boronate esters, via the Boron-Wittig reaction.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
客戶也查看了
A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates
Journal of the American Chemical Society, 136, 6534-6537 (2014)
Organic letters, 17(7), 1708-1711 (2015-03-24)
A highly stereoselective boron-Wittig reaction between stable and readily accessible 1,1-bis(pinacolboronates) and aldehydes furnishes a variety of synthetically useful di- and trisubstituted vinyl boronate esters.
文章
Enantioselective alkene diboration is a valuable strategy for transforming unsaturated hydrocarbons into useful chiral building blocks.
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