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Merck
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重要文件

74437

Sigma-Aldrich

(+)-香柏酮

≥99.0% (GC)

同義詞:

(4R,4aS,6R)-4,4a,5,6,7,8-六氢-4,4a-二甲基-6-(1-甲基乙烯基)-2(3H)-萘酮

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About This Item

經驗公式(希爾表示法):
C15H22O
CAS號碼:
分子量::
218.33
Beilstein:
4676969
EC號碼:
MDL號碼:
分類程式碼代碼:
12352205
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥99.0% (GC)

形狀

crystals

光學活性

[α]20/D +182.0±5.0°, c = 1% in ethanol

儲存條件

under inert gas (Argon)

mp

35-39 °C

官能基

ketone

儲存溫度

2-8°C

SMILES 字串

C[C@@H]1CC(=O)C=C2CC[C@H](C[C@@]12C)C(C)=C

InChI

1S/C15H22O/c1-10(2)12-5-6-13-8-14(16)7-11(3)15(13,4)9-12/h8,11-12H,1,5-7,9H2,2-4H3/t11-,12-,15+/m1/s1

InChI 密鑰

WTOYNNBCKUYIKC-JMSVASOKSA-N

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一般說明

(+)-诺卡酮(Nootkatone)是一种双环共轭倍半萜酮,具有葡萄柚香味,常用于香料、食品、化妆品和医药行业。它可以由(+)-瓦伦烯通过生物转化反应合成。(+)-诺卡酮是香附子(一种著名的中药)抗血小板作用的活性成分。它还具有抗金黄色葡萄球菌生物被膜形成的强效作用。

應用

(+)-诺卡酮可用于:
  • 光照条件下与有机叠氮化物进行铁(III)卟啉催化的烯烃的氮杂环丙烷化反应。
  • 作为底物通过铱催化的还原消除反应合成相应的三烯衍生物。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Skin Sens. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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