684821

二乙酸-1,2-双(苯亚磺酰)乙基钯(II)

• 同義詞: White 催化剂
• 經驗公式（希爾表示法）: C₁₈H₂₀O₆PdS₂
• CAS號碼: 858971-43-4
• 分子量：: 502.90
• MDL號碼: MFCD09842752
• 分類程式碼代碼: 12161600
• PubChem物質ID: 329760926
• NACRES: NA.22

屬性

• 形狀: powder
• 反應適用性: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: C-H Activation
• 環保替代產品特色: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 環保替代類別: Aligned,
• 儲存溫度: −20°C
• SMILES 字串: CC(=O)O[Pd]OC(C)=O.O=S(CCS(=O)c1ccccc1)c2ccccc2
• InChI: 1S/C14H14O2S2.2C2H4O2.Pd/c15-17(13-7-3-1-4-8-13)11-12-18(16)14-9-5-2-6-10-14;2*1-2(3)4;/h1-10H,11-12H2;2*1H3,(H,3,4);/q;;;+2/p-2
• InChI 密鑰: SNNYSJNYZJXIFE-UHFFFAOYSA-L

描述

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

應用

White Catalyst: A Catalyst for Allylic C–H Oxidation and Amination

Macrolactonization via Hydrocarbon Oxidation

Catalyst for allylic C-H oxidation, useful for preparation of branched allylic esters, macrocycles, and amino alcohol derivatives.

安全資訊

• 象形圖: GHS05
• 訊號詞: Danger
• 危險聲明: H318
• 防範說明: P280 - P305 + P351 + P338
• 危險分類: Eye Dam. 1
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves