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重要文件

683140

Sigma-Aldrich

双(1,5-环辛二烯)四氟硼酸铑(I) 水合物

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About This Item

經驗公式(希爾表示法):
C16H24BF4Rh · xH2O
CAS號碼:
分子量::
406.07 (anhydrous basis)
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

形狀

powder

品質等級

反應適用性

core: rhodium
reagent type: catalyst

mp

165 °C (dec.) (lit.)

SMILES 字串

O.[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.BF4.H2O.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;;/h2*1-2,7-8H,3-6H2;;1H2;/q;;-1;;+1/b2*2-1-,8-7-;;;

InChI 密鑰

NYMNQNLSUITCLM-DIURZKMRSA-N

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相關類別

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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文章

Asymmetric hydrogenation plays an important role in today’s synthesis world. Knowles and Noyori pioneered this field and were rewarded with the Nobel Prize in 2001 for their work.

Asymmetric hydrogenation plays an important role in today’s synthesis world. Knowles and Noyori pioneered this field and were rewarded with the Nobel Prize in 2001 for their work.

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions.

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions. 20 different precatalyst complexes are available, providing access to hundred different catalytic reactions.

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