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About This Item
經驗公式（希爾表示法）:
C32H56Cl2Rh2
CAS號碼:
分子量：:
717.50
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22
推薦產品
化驗
98%
形狀
powder
反應適用性
core: rhodium
reagent type: catalyst
mp
190 °C (dec.) (lit.)
SMILES 字串
Cl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4
InChI
1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChI 密鑰
GQPAPAIPOLEZHT-XFCUKONHSA-L
相關類別
應用
双环辛烯氯化铑(I)二聚体可用作以下反应的催化剂：
- 通过芳基硼酸与α,β-不饱和磺酰基化合物的不对称1,4-加成，合成富对映体的偕二芳基磺酸盐。
- N脱保护吲哚和吡咯的直接C-芳基化。
- 通过C-H键活化的在芳烃羧化反应。
訊號詞
Warning
危險分類
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
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文章
Direct Arylation of Heterocycles
Lewis and co-workers have recently disclosed a highly functional-group compatible Rh-catalyzed C-H bond activation for the rapid synthesis of functionalized heterocycles.
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