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Merck
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文件

205036

Sigma-Aldrich

三(三苯基膦)氯化铑(I)

99.9% trace metals basis

同義詞:

NSC 124140, RhCl (PPh 3 ) 3, Wilkinson 催化剂, 三(三苯膦基)氯化铑(I)

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About This Item

線性公式:
[(C6H5)3P]3RhCl
CAS號碼:
14694-95-2
分子量：:
925.22
Beilstein:
4581440
EC號碼:
238-744-5
MDL號碼:
MFCD00010016
分類程式碼代碼:
12161600
PubChem物質ID:
24852305
NACRES:
NA.22

化驗

99.9% trace metals basis

反應適用性

core: rhodium
reagent type: catalyst

SMILES 字串

Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1

InChI 密鑰

IXAYKDDZKIZSPV-UHFFFAOYSA-M

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相關類別

應用

硅氢化催化剂

用于许多有机反应的催化剂，包括：
  • 化学选择性烯丙基烷基化
  • Si-H 键的化学计量活化 与硅氢化反应
  • 烯烃分子间和分子内加氢酰化（含助催化剂）
  • 二有机硅烷的聚合
用于芳基硼酸与活化的烯基甲苯磺酸酯进行交叉偶联反应的有效催化剂。也用于催化 DABCO 作用下烯丙基酚醚裂解为酚。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H317,H413

危險分類

Aquatic Chronic 4 - Skin Sens. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

個人防護裝備

Eyeshields, Gloves, type N95 (US)

分析證明 (COA)

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Sonsoles Rodriguez Aristegui et al.
Organic letters, 8(26), 5927-5929 (2006-12-15)
[Structure: see text] 2-morpholin-4-yl-4-oxo-4H-chromen-8-yl 2,2,2-trifluoromethanesulfonate is a key intermediate for the synthesis of the DNA-dependent protein kinase (DNA-PK) inhibitor 8-dibenzothiophen-4-yl-2-morpholin-4-yl-chromen-4-one (NU7441). Two improved methods for the synthesis of this triflate have been developed: (A) in 35% overall yield, through modification
European Journal of Organic Chemistry, 5260-5260 (2006)
Effect of catalytic hydrogenation of cellular lipid and fatty acid on the susceptibility of tumor cells to humoral immune killing.
S I Schlager
Methods in enzymology, 73(Pt B), 191-199 (1981-01-01)
V P Shevchenko et al.
Bioorganicheskaia khimiia, 36(2), 283-288 (2010-06-10)
1,2-Tritium-labeled 3-(O-carboxypropyl)- and 3-(O-carbomethoxypropyl)-oximes of 6alpha-methyl-16alpha,17alpha-cyclohexanopregn-4-ene-3,20-diones were obtained by the homogeneous catalytic hydrogenation of 1,2-dehydroprecursors with gaseous tritium and the subsequent separation of the resulting mixtures by HPLC. The specific radioactivities of 50-55 Ci/mmol were prepared using tris-(triphenylphosphine)-rhodium chloride.
P Andrew Evans et al.
Journal of the American Chemical Society, 124(30), 8782-8783 (2002-07-26)
Transition metal-catalyzed cycloaddition reactions represent powerful methods for the construction of complex polycyclic systems. We have developed a new intermolecular metal-catalyzed [4 + 2 + 2] cycloaddition of heteroatom-tethered enyne derivatives with 1,3-butadiene. This study demonstrates that excellent selectivity can
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