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About This Item
線性公式:
MnCl2 · xH2O
CAS號碼:
分子量::
125.84 (anhydrous basis)
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22
推薦產品
化驗
99.999% trace metals basis
反應適用性
core: manganese
reagent type: catalyst
mp
122 °C (lit.)
密度
1.913 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
O.Cl[Mn]Cl
InChI
1S/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2
InChI 密鑰
BXRRQHBNBXJZBQ-UHFFFAOYSA-L
應用
Starting material for preparation of organomanganese chloride reagents; Catalyst for reductionof vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- and stereo-selectively.
訊號詞
Danger
危險分類
Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - STOT RE 2
標靶器官
Brain
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類(WGK)
WGK 2
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
客戶也查看了
Cahiez, G.; Laboue, B.
Tetrahedron Letters, 33, 4439-4439 (1992)
Fujii, H.; Oshima, K.; Utimoto, K.
Tetrahedron Letters, 32, 6147-6147 (1991)
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