13220

氯化亚锰 一水合物

≥97.0%

• 同義詞: Manganese dichloride monohydrate
• 線性公式: MnCl₂ · H₂O
• CAS號碼: 64333-01-3
• 分子量：: 143.86
• EC號碼: 231-869-6
• MDL號碼: MFCD00149793
• 分類程式碼代碼: 12161600
• PubChem物質ID: 57646988
• NACRES: NA.22

屬性

• 品質等級: 200
• 化驗: ≥97.0%
• 形狀: powder
• 反應適用性: core: manganese; reagent type: catalyst
• 雜質: ≤0.01% heavy metals (as Pb)
• 負離子痕跡: sulfate (SO₄^2-): ≤1000 mg/kg
• 正離子痕跡: Fe: ≤200 mg/kg
• SMILES 字串: O.Cl[Mn]Cl
• InChI: 1S/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2
• InChI 密鑰: BXRRQHBNBXJZBQ-UHFFFAOYSA-L

描述

應用

Starting material for preparation of organomanganese chloride reagents; in combination with RLi or RMgX catalyzes reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- andstereo-selectively.

安全資訊

• 象形圖: GHS06,GHS08,GHS05,GHS09
• 訊號詞: Danger
• 危險聲明: H301,H318,H373,H411
• 防範說明: P260 - P273 - P280 - P301 + P310 - P305 + P351 + P338 - P314
• 危險分類: Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2
• 標靶器官: Brain
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 2
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves