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Key Documents

46210

Sigma-Aldrich

(+)-葑酮

purum, ≥98.0% (sum of enantiomers, GC)

同義詞:

(+)-1,3,3-三甲基-2-降冰片酮, (1S)-1,3,3-三甲基二环[2.2.1]庚-2-酮

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About This Item

經驗公式(希爾表示法):
C10H16O
CAS號碼:
分子量::
152.23
Beilstein:
2206555
EC號碼:
MDL號碼:
分類程式碼代碼:
12352212
PubChem物質ID:
NACRES:
NA.22

等級

purum

品質等級

化驗

≥98.0% (sum of enantiomers, GC)

光學活性

[α]20/D +60±3°, neat

折射率

n20/D 1.463

bp

63-65 °C/13 mmHg (lit.)

mp

5-7 °C (lit.)

密度

0.945 g/mL at 20 °C (lit.)

官能基

ketone

SMILES 字串

CC1(C)[C@@H]2CC[C@@](C)(C2)C1=O

InChI

1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

InChI 密鑰

LHXDLQBQYFFVNW-XCBNKYQSSA-N

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儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

150.8 °F - closed cup

閃點(°C)

66 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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M Miyazawa et al.
Xenobiotica; the fate of foreign compounds in biological systems, 37(2), 194-204 (2007-05-09)
The in vitro metabolism of (-)-fenchone was examined in human liver microsomes and recombinant enzymes. The biotransformation of (-)-fenchone was investigated by gas chromatography-mass spectrometry. (-)-Fenchone was found to be oxidized to 6-exo-hydroxyfenchone, 6-endo-hydroxyfenchone and 10-hydroxyfenchone by human liver microsomal
I M Isa et al.
Talanta, 87, 230-234 (2011-11-22)
A new cobalt(II) ion selective electrode based on palladium(II) dichloro acetylthiophene fenchone azine(I) has been developed. The best membrane composition is found to be 10:60:10:21.1 (I)/PVC/NaTPB/DOP (w/w). The electrode exhibits a Nerstian response in the range of 1.0 × 10(-1)-1.0
Jeannette Nuessli et al.
International journal of biological macromolecules, 33(4-5), 227-234 (2003-11-11)
Amylose complexes were prepared, as lamellar single crystals and polycrystalline powders, from aqueous solutions by adding small flavor molecules. The morphology, crystal structure, and thermal properties of complexes with fenchone, menthone, and geraniol were determined using transmission electron microscopy, wide-angle
B Simándi et al.
Journal of agricultural and food chemistry, 47(4), 1635-1640 (1999-11-24)
Ground fennel seeds were extracted with supercritical carbon dioxide. Small-scale subsequent extractions of the same sample showed that the composition of volatile compounds was changed with the extension of extraction time and only principal volatile components (limonene, fenchone, methylchavicol, and
Giovanna Longhi et al.
The journal of physical chemistry. A, 110(15), 4958-4968 (2006-04-14)
We report and discuss the infrared (IR) vibrational circular dichroism (VCD) spectra of the enantiomeric pairs of the olefin derivatives of fenchone (1,3,3-trimethyl-2-methylenebicyclo[2.2.1]heptane) and camphor (1,7,7-trimethyl-2-methylenebicyclo[2.2.1]heptane), respectively, together with those of the parent molecules. The VCD spectra were taken in

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