推薦產品
品質等級
化驗
≥98%
形狀
liquid
光學活性
[α]24/D −50.5°, neat
折射率
n20/D 1.461 (lit.)
bp
192-194 °C (lit.)
mp
5-6 °C (lit.)
密度
0.948 g/mL at 25 °C (lit.)
官能基
ketone
SMILES 字串
CC1(C)C2CCC(C)(C2)C1=O
InChI
1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m0/s1
InChI 密鑰
LHXDLQBQYFFVNW-OIBJUYFYSA-N
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一般說明
(1R)-(-)-葑酮是在茴香油和金钟柏油中发现的桥连双环酮 。
應用
(1R)-(-)-葑酮与吡啶基烷基胺进行缩合形成手性亚氨基吡啶配体,这些配体可用于对映选择性铜催化的亨利(硝基羟醛)反应。它也可以用于制备对映体C(7)-抗取代的 Fenchones 作为新的手性来源。
危險聲明
危險分類
Aquatic Chronic 2
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 2
閃點(°F)
151.7 °F - closed cup
閃點(°C)
66.5 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
客戶也查看了
(1R)-(-)-Fenchone.
Acta Crystallographica Section E, Structure Reports Online, 57(11), o1034-o1035 (2001)
First access to enantiopure C (7)-substituted fenchones: new norbornane-based chiral materials from the chiral pool.
Tetrahedron Asymmetry, 14(12), 1607-1609 (2003)
Regio-and stereochemical course of the ring expansion of bridged bicyclic ketones to spirocyclic a-keto tetrahydrofurans.
The Journal of Organic Chemistry, 57(14), 3956-3965 (1992)
Modular iminopyridine ligands. Application to the enantioselective copper (II)-catalyzed Henry reaction.
Tetrahedron Asymmetry, 17(14), 2046-2049 (2006)
Natural product communications, 4(8), 1103-1106 (2009-09-23)
The essential oils from leaves and inflorescences of L. cariensis Boiss. and L. stoechas L. subsp. stoechas collected in Greece were analyzed by GC and GC/MS. In the inflorescences and leaves essential oils of L. cariensis the most abundant metabolite
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