455164

三环己基磷 溶液

20 wt. % in toluene

• 同義詞: NSC 158657, PCy₃
• 線性公式: (C₆H₁₁)₃P
• CAS號碼: 2622-14-2
• 分子量：: 280.43
• Beilstein: 957171
• MDL號碼: MFCD00003853
• 分類程式碼代碼: 12350000
• PubChem物質ID: 24869033
• NACRES: NA.22

屬性

• 品質等級: 100
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Cross Couplings
• 濃度: 20 wt. % in toluene
• 官能基: phosphine
• SMILES 字串: C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
• InChI: 1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2
• InChI 密鑰: WLPUWLXVBWGYMZ-UHFFFAOYSA-N

描述

應用

Catalyst for:

• Carbonylative Suzuki-coupling of benzyl halides with potassium aryltrifluoroborates
• Suzuki-Miyaura reactions of aryl sulfonates / halides with arylboronic acids
• Synthesis of an acromelic acid A analog based 11C-labeled PET tracer
• Synthesis of (-)-Exiguolide and its analogues
• Allylation of zinc enolates

Reagent used as a ligand for a range of metal-catalyzed organic transformations.

安全資訊

• 象形圖: GHS02,GHS08,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H304,H315,H319,H335,H336,H361d,H373,H412
• 防範說明: P210 - P273 - P301 + P310 - P303 + P361 + P353 - P305 + P351 + P338 - P331
• 危險分類: Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
• 標靶器官: Central nervous system, Respiratory system
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 51.8 °F - closed cup
• 閃點（°C）: 11 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter