398799

二氯(1,10-菲咯啉)钯(II)

• 經驗公式（希爾表示法）: C₁₂H₈Cl₂N₂Pd
• CAS號碼: 14783-10-9
• 分子量：: 357.53
• MDL號碼: MFCD00192008
• 分類程式碼代碼: 12161600
• PubChem物質ID: 24864767
• NACRES: NA.22

屬性

• 反應適用性: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• SMILES 字串: Cl[Pd]Cl.c1cnc2c(c1)ccc3cccnc23
• InChI: 1S/C12H8N2.2ClH.Pd/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;/q;;;+2/p-2
• InChI 密鑰: YGAISFRMWCCXCG-UHFFFAOYSA-L

描述

應用

Catalyst for:

• Carbonylation of alkyl nitrites
• Arylation reactions
• Multiple acetylene insertions under Sonogashira reaction protocol
• Cross-coupling reactions of pyridine carboxylic acid chlorides with alkylzinc reagents
• Hydrophosphinylation of alkenes and alkynes
• Heck reaction
• Regioselective and stereoselective aminohalogenation reactions
• Reaction of chloroenynes and chlorodienes with Grignard reagents for the synthesis of stereodefined enynes and dienes

• Affects the aggregation of human prion protein PrP106-126

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable