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About This Item
線性公式:
(CH3)3SiCl
CAS號碼:
分子量：:
108.64
Beilstein:
1209232
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.22
推薦產品
形狀
liquid
濃度
1.0 M in THF
密度
0.88 g/mL at 25 °C
SMILES 字串
C[Si](C)(C)Cl
InChI
1S/C3H9ClSi/c1-5(2,3)4/h1-3H3
InChI 密鑰
IJOOHPMOJXWVHK-UHFFFAOYSA-N
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一般說明
Chlorotrimethylsilane (TMSCl) is a silylating agent employed in the silylation of alcohols, amines, carboxylic acids, thiols, and other functional groups. Silyl group serves as a protecting group for these original functional groups.
應用
Chlorotrimethylsilane (TMSCl) can be used as a reagent:
- To synthesize allenylsilane via carbolithiation of conjugated enynes with aryllithium.
- In the reductive coupling of aldehydes and ketones to produce corresponding 1,2 diols in the presence of zirconocene dichloride and magnesium.
- To prepare 4,4′-bis(trimethylsilyl)bicyclohexyl-2,2′-diene from 1,3-cyclohexadiene by reductive disilylation reaction.
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
-4.0 °F - closed cup
閃點（°C）
-20 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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