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About This Item
經驗公式（希爾表示法）:
BCl3
CAS號碼:
分子量：:
117.17
MDL號碼:
分類程式碼代碼:
12352106
PubChem物質ID:
NACRES:
NA.22
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蒸汽密度
4.03 (vs air)
蒸汽壓力
1 mmHg ( 12.7 °C)
形狀
liquid
反應適用性
core: boron
reagent type: Lewis acid
reagent type: catalyst
濃度
1.0 M in p-xylene
密度
0.901 g/mL at 25 °C
SMILES 字串
ClB(Cl)Cl
InChI
1S/BCl3/c2-1(3)4
InChI 密鑰
FAQYAMRNWDIXMY-UHFFFAOYSA-N
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應用
用于制备脂肪酸甲酯以及用于三酸甘油酯的酯交换反应。
訊號詞
Danger
危險分類
Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Repr. 1B - Skin Corr. 1B - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
84.2 °F - closed cup
閃點（°C）
29 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Guillaume Reinisch et al.
The journal of physical chemistry. A, 115(18), 4786-4797 (2011-04-16)
We report on a theoretical study of the gas-phase decomposition of boron trichloride in the presence of hydrogen radicals using ab initio energetic calculations coupled to TST, RRKM, and VTST-VRC kinetic calculations. In particular, we present an addition-elimination mechanism (BCl(3)
Novel polyhydroxylated cyclic nitrones and N-hydroxypyrrolidines through BCl3-mediated deprotection.
Stéphanie Desvergnes et al.
Organic letters, 10(14), 2967-2970 (2008-06-24)
A general method to prepare a new class of carbohydrate-derived, enantiomerically pure polyhydroxypyrroline N-oxides from their alkoxy (protected) derivatives is presented. Boron trichloride is shown to cleave efficiently benzyl ethers and ketals without affecting the imine N-oxide functionality of nitrones.
Stephen Sproules et al.
Inorganic chemistry, 50(10), 4503-4514 (2011-04-19)
Sky-blue Tp*WOCl(2) has been synthesized from the high-yielding reaction of Tp*WO(2)Cl with boron trichloride in refluxing toluene. Dark-red Tp*WOI(2) was prepared via thermal decarbonylation followed by aerial oxidation of Tp*WI(CO)(3) in acetonitrile. From these precursors, an extensive series of mononuclear
Lei Zhang et al.
Journal of combinatorial chemistry, 8(3), 361-367 (2006-05-09)
A novel and efficient microwave-assisted, BCl(3) mediated coupling reaction to synthesize o-(hydroxyaryl)(aryl)methanone structures from phenols and acyl chlorides is described. This reaction was further incorporated into a two-step synthesis of biologically interesting xanthones.
Dean Marković et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(20), 5969-5975 (2010-04-17)
The first ene reactions of SO(2) and unfunctionalized alkenes are reported. Calculations suggest that the endergonic ene reactions of SO(2) with alkenes can be used to generate beta,gamma-unsaturated sulfinyl and sulfonyl compounds. Indeed, in the presence of one equivalent of
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