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344249

Sigma-Aldrich

氯磷酸二苯酯

96%

同義詞:

二苯基氯磷酸酯, 二苯磷酰氯

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About This Item

線性公式:
(C6H5O)2POCl
CAS號碼:
分子量::
268.63
Beilstein:
654130
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

10 mmHg ( 190 °C)

化驗

96%

形狀

liquid

折射率

n20/D 1.55 (lit.)

bp

314-316 °C/272 mmHg (lit.)

密度

1.296 g/mL at 25 °C (lit.)

SMILES 字串

ClP(=O)(Oc1ccccc1)Oc2ccccc2

InChI

1S/C12H10ClO3P/c13-17(14,15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H

InChI 密鑰

BHIIGRBMZRSDRI-UHFFFAOYSA-N

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一般說明

Diphenyl phosphoryl chloride is a diaryl phosphoryl derivative. It is formed during the preparation of monophenyl phosphoryl chloride via reaction of phenol and phosphorus oxychloride.

應用

Diphenyl phosphoryl chloride may be used:
  • in the preparation of guanosine-adenosine-5′,5′-triphosphate, guanosine-cytidine-5′,5′-triphosphate, guanosine-uridine-5′,5′-triphosphate, diguanosine-5′,5′-diphosphate and diguanosine-5′,5′-triphosphate
  • as phosphorylating agent for the synthesis of 2-deoxy-D-galactose-3 and -6 phosphoric acids
  • in the synthesis of diaryl phosphoryl derivatives of alkylene dithiophosphates

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

>235.4 °F - closed cup

閃點(°C)

> 113 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


分析證明 (COA)

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Y Furuichi et al.
The Journal of biological chemistry, 251(16), 5043-5053 (1976-08-25)
Blocked and methylated 5' termini of reovirus mRNA are formed by viral cores at an early stage of transcription. Cores incubated in a complete transcription reaction mixture for 30 s, or in a mixture lacking UTP and ATP for a
Dialkyl (aryl) phosphoryl derivatives of alkylene dithiophosphates.
Sharma CS and Nagar PN.
Phosphorus, Sulfur, and Silicon and the Related Elements, 179(9), 1793-1798 (2004)
219. Deoxy-sugars. Part XV. D-Galactose-3 and-6 phosphoric acids and their 2-deoxy-analogues.
Foster AB, et al.
Journal of the Chemical Society, 980-987 (1951)
Synthesis of Disodium Phenyl Phosphate.
Freeman HF and Colver CW.
Journal of the American Chemical Society, 60(4), 750-751 (1938)

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